Katherine Pierce from The Vampire Diaries
When it comes to famous vampires, we have to talk about Damon Salvatore. Katherine Pierce is a former lover of Damon and Stefan Salvatore in The Vampire Diaries. Katherine is first shown in flashbacks, showing her romantic relationship with Salvatore.
Katherine, played by Nina Dobrev, turned to the Salvatore brothers, but she was eventually captured by the people of Mystic Falls. Even though she has a sweet nature, her mysterious side is shown when she escapes her death with the help of George Lockwood.